Nano-Grid[n]arenes: A Diverse Platform of Covalently Hierarchical Meta-molecules: (AOICS) - Lupine Publishers

Nano-Grid[n]arenes: A Diverse Platform of Covalently Hierarchical Meta-molecules by Linghai XIE in Archive of organic and inorganic chemical sciences(AOICS) in Lupine Publishers

In the background of the era of consciousness (EOC) from carbon to robot, we proposed an alternative way via the nanoarchitectures to challenge suspended issues from plastic electronics. Covalent meta-molecules with the features of structural diversity, hierarchy and cross-scale have absolute advantages to decode the universe law of matter and to explore the advanced materials. In the past decade, we focus on a versatile C (sp3)- C (sp2) reaction of fluorenol’sFrediel-Crafts protocol (FOH’s FCP) [1] as a tool of molecular installing technology, associated with the Pd-catalyzed (sp2)- C (sp2) coupling reaction such as Suzuki cross-coupling reaction. A series of the complex di aryl fluorine’s (CDAFs), have been synthesized, including small molecules, polymers, as well as covalent nanostructures via the An+Bn and/ or Ann modes where A represents for fluorine’s (from Alcohol) and Before benzene substrates [2-8]. Recently, we discoverednano-gridarenes that is a huge family of organic unit nanogrids [9], multigrids [10] as well as polygrids [11] after the exploration of fluorine-based nano synthesis ten year age [12]. Grid polymers serve as the advanced soluble nanopolymers with potential application of light-emitting diodes, lasers, solar cells and memory [13].

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